Playing around with the toe-in will definitely alter the soundstage. The less toe-in the wider the soundstage, usually. One can also angle both speakers towards the opposite ear or beyond. Gotta experiment. After adjusting, check the center "phantom" image. Don't let a hole open up. If one does, move the speakers closer.
Also, the listening position should be at least 3 ft. from the wall behind it to avoid bass peaking. Absorbing traps behind both the speakers and the listening position will also help. First reflections must be accounted for, as mentioned by someone else.

