My limited XLR experience
XLR is not always properly implemented, so verify if you can. Perhaps others can give advice about this.
Short runs in home systems, I do not believe we need the improved shielding, but it doesn't hurt anything.
Locking XLR connectors are nice, I changed all my RCAs to locking type connectors. Moving any cable can inadvertently disrupt a connection.
Signal Strength: Not always, but most often I think, (if implemented correctly) XLR signal strength is higher than RCA, and this can allow you to keep a volume control in a more advantageous position, or drive equipment 'less hard'.
I have heard volume differences, but not any perceived 'better' or 'preferred' sound when I have tried alternate outputs/inputs.

