OP:
IMHO, rhodium should never be considered. It's just too hard to grip well and doesn't conduct very well. Gold had the least oxidation, but I love me the silver plated one's. :)
Pure copper is a great choice, but will require regular maintenance.
Bananas rule, spades drool. End of discussion.
I just checked my speaker connections. All using bananas, all nice and tight.
The number of times I’ve had spades get loose instead though.....
Point is, and it really is kind of a tongue in cheek thing, bananas beat spades for long term reliability in almost all setups. If you have to use a Cardas or Mundorf speaker terminal to ensure your spades stay tight it kind of proves my point.