go to usedcable.com and do the home test and buy the one you like...Plenty to chose from...And only you can decide.
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The difference between the materials is easy to generalize however the material does not have as big an impact as the entir package. The sound you get will depend on gauge the braid if it is braided the sheilding, the source cable quality etc. otherwise I would recommend copper but most are mediocre. Silver is expensive band not particularily the best choice for a slamming SS amp. Save your money and get Cardas Golden (fill in the blank it changes often) perfections. They are euphonic and as warm as a nice fire on a winter day.
there is no reason to look at the question as one of exclusivity. have you considered silver coated copper ?
my current reference cable is ear to ear black. you might want to consider an audition. as i hear it, it provides a low noise, grain free, balanced presentation.
you can read my review on audiophilia.com.