I also use a very similar DAC/amp dongle but strictly for use on my ipad to headphone connection that I only use when in bed next to my sleeping wife. It did indeed improve the sound pretty remarkably, to the point that I sometimes wonder "why do I even need that expensive "proper" headphone rig?" Then I go listen to that rig and say, "oh yeah, that's why". But that's not really a fair comparison since those are significantly better HP's. I'd try them with the dongle but I really doubt it has enough juice to drive them. They take a ton of power for HP's.
I'd still highly recommend one of these dongles for anyone that doesn't want to commit to buying a bunch of equipment to use with HP's.

