Preamp for sure. Digital volume controls are almost universally bad at low volume. Only one that I found almost as good as my preamps on low volume was the Leedh volume algorithm on the Lumin streamers and DACs.
I have owned the Benchmark LA4 and the Holo Audio Serene at the same time. I now have the Benchmark HPA4 and the Schiit Audio Kara F.
The HPA4/LA4 are super neutral, and I use it with a slightly warm CODA #16.
The Serene is a bit warmer than the HPA4/LA4 and likely a better match with the Puriffi amps you have.
The slightly warm Kara F is not as good as the Serene but cost $700 and I am enjoying the heck out of it with the Schiit Wotan amp and Magnepan Mini panels. I did not want to spend more on the preamp than the cost of the amp and Mini. It was a good move in retrospect. The HPA4 in place of the Kara improves the system but the Kara is not that far behind. This is the new version of the Kara.
BTW - I have only heard 1 preamp that I thought was better than the LA4 or HPA4 in my system. It was the new $33k Allnic Signature OTL/OCL I am getting the Allnic DAC that costs a lot but not the preamp because the HPA4 is pretty spectacular.
BTW2 - the $2k Wotan amp is a incredible value and preferred by me over the Class D amps I have owned in the past including GAN. It is a great overall package.
BTW3 - I recently repurchased the Schiit Mjolnir 3 (MJ3) headphone amp / preamp. Previously It replaced the Serene and I liked it a lot for 2-channel (never heard it on headphones). After a while though I wanted a bit less warmth on the Mini. Today, I have some demo Focal Utopia headphones and the MJ3 is great with it. Keeping both.

