Maybe it's your Network.
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Agreed, it's probably the network or interference from some other device (portable phone, remote printer, etc.). It could also be in some of the buffer settings within iTunes. I can't recall which are the usual suspects but you might do a search on optimizing iTunes/airport express streaming settings. Short of that an ethernet connection should solve it, but that defeats the advantages of wireless. If iTunes is not doing the same stalling while listening on your native host computer (not streaming) then you know it is not iTunes, but the network