Have not heard the Aerials, I do have a James center center channel speakers flanked by two VSA 4jr's. But my experience with the James is very good. Sound and built quality are excellent.
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I have heard both and own (for sale here)the previous versionof the S103s, Grand Symphonic 10s with a 83 center from James. They sound great! More bottom than the Aerials and smoother on the highs. The Aerials are a fine speaker as well, but for the twice the price. I would keep them, but moved and my room is way to small for them.