I like Neil Young's music, but as a technical guitarist, he doesn't make any list, top 100 or even top 500. That's OK. Neil plays guitar very well for what he needs to do - accompany his voice. But he is no virtuoso on the guitar, and why should he be? There are many excellent guitar players out there, from Jeff Beck to Steve Howe... and some that you probably didn't know about. (Check out Glen Campbell on YouTube sometime, or give James Taylor a good listen.)
And remember that VERY few rock guitarist could hang with the real virtuosos, like Joe Pass, Herb Ellis, Kenny Burrell, Barney Kessel, George Benson, Pat Martino, Tal Farlow, Stanley Jordan and on and on and on...
Neil Young is a great singer & songwriter. He never aspired to be a great guitarist.