Like another has said, the negative-polarity signal pin in an XLR-to-RCA cable is usually connected to ground/shield (if at all). There is no benefit to getting an XLR-to-RCA cable instead of just an RCA cable unless the XLR connector on the one side is superior to what RCA connector is available. There is absolutely no signal difference between these cables, as the target devices (i.e. amp) will only use the one RCA signal wire anyways. The only real benefit that you might get is if you run a true XLR cable and then use a Jenson Transformer XLR-to-RCA converter right next to the amplifier. You're spending a lot more money here.
Better off just to get a really good RCA cable in this situation.