Ah, the joys of computer audio. Sorry I can't help but I feel your pain.:(
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Try reloading the program and make sure you get 1.89d4 This fixes any iTunes 11 issues.
I too use a Mac mini that I upgraded from 4 to 8 gig. If the Mac recognizes the RAM it's fine.
I had a big issue when I loaded ITunes 11. It just wouldn't work right. First, it would try to load a full album into the RAM and then wouldn't play. I turned off gapless play, then it wouldn't do this and went back to loading only one song at time. But, it would never play the first song selected with memory play. You would see loading but no sound. You had to hit another song, it would load and then work. You could then go back and play the first song.
Mine now works perfect. If you continue to have issues, contact PM.
I tried Pure Musics trial and did not think it was an upgrade to the sound. But, what do I know? Not much about computer audio but very very basic stuff. I have tried to educate myself at computeraudiophile.com, here, AA and Empirical Audio site, but there are still plenty of holes in my understanding, with all the acronyms, and technical jargon that is spit out like its a language we already know. Just my rant. I use a Macbook Pro and W4S2 DAC. Did not think much of Pure Music. I wish someone, anyone would publish the quintessential book, "Computer Audio for Dummies." Every other field has a "dummy book."
After receiving an email from Pure Music I downloaded version 1.89d4 which had to be manually downloaded (not automatically) and I'm back and running now. Very please, quite the learning curve as I'm a PC guy and have never used Pure Music or other software before. From a sound quality standpoint it's incredible...
Well, I'm having problems with itunes 11 and Audirvana as it will load music into a new feature of 11 called "up next". It loaded 9,779 songs after I hadn't used my system for a couple of days over the holiday, and pissed my mac mini off so I had to dump them all in the trash. Didn't lose the music but what a pita. Right after 11 came out 11.1 came out.......... I wonder why?