I listen WCRB in Boston (my home town) for classical and I like the BBC stations for rock.
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WHRB for Jazz in the am, classical in the afternoon and classical and MET Opera on Saturdays. The schedule is on the website.
WCRB has the BSO on Saturday evenings, and in the summer, Tanglewood broadcasts on Friday evenings.Opera and early music on Sunday nights.
WGBH has good jazz from 8:00 pm-5:00 am.
All times are Eastern.