Your idea will work and sound great. I've been doing this for a couple of years and am now using two pairs of monoblocks to drive my Salons with. The extra headroom is a big plus and according to Kevin Voecks at Revel, even thought there is not and electronic crossover, by biamping this way, the amps do see the circuit differently and work more efficently in this configuration than with using one stereo amp. In my experience, it is better to use the exact same isolatoin, amps, interconnects, etc., for vertical biamping to sound its best. Otherwise with a high rez system, the bass midrange and treble sound differently and not as coherent. Good luck!
Steven
Steven